Given two similar definitions, it is very valuable to have a counterexample distinguishing them. Here is one case where this arises: A Hurewicz fibration $p:E\to B$ of unbased spaces is a continuous map such that for every space $X$ and every commutative diagram
$$\begin{matrix} X & \longrightarrow & E\\ \downarrow & ~ & \downarrow \\ X\times I & \longrightarrow & B\end{matrix}$$
there exists a map $X\times I\to E$ making the resulting diagram commute. On the other hand, a Serre fibration $p:E\to B$ is a continuous map with the same property for every CW-complex $X$. From the definition it seems that there might be Serre fibrations that are not Hurewicz fibrations. In fact, there are! An example first appeared in R. Brown’s paper [1] in 1966. We define $E$ to be the subset of the Euclidean plane $\R^2$ defined by
$$
E = \{ (x,y) : x\in [0,1], y = 1/n\text{ for some } n\in \N_{>0} \}\cup \{ (x,x-1) : x\in [0,1]\}
$$
We take the base space $B$ to be $B = [0,1]$, and the map $p:E\to B$ is defined by $p(x,y) = x$. The fiber is then the set of poins in $[0,1]$ of the form $1/n$ or $0$. Here is a picture of this situation:
(See the bottom of the post for Tikz code). This is a Serre fibration, since the image of any map $[0,1]^n\to E$ actually has to land in a connected component of $E$ (and this is the reason for the diagonal tail).
However, the composed map $F\to B$ is just the constant map $1$. The homotopy of this map with the constant map 0 cannot factor through $E$. Indeed, if there were such a factorisation, i.e. a homotopy $F:F\times I\to E$ then the composed map $F\to F\times I\to E$ where $F\to F\times I$ is given by $x\mapsto (x,1)$ would map $F$ a compact set to a noncompact set (shown projected into the vertical line).
[1] Brown, R. Two examples in homotopy theory. Proc. Cambridge Philos. Soc. 62 1966 575–576. MR0205252
Here is the LaTeX code for the diagram (needs \usepackage{tikz} in the preamble):
\begin{tikzpicture}[scale=2.5]
%%draw fiber
\foreach \x in {1,2,...,60} {
\node at (1,1.5 + 1/\x) [circle,draw=blue,fill=blue,scale=0.1] {};
}
\node at (1,1.5) [circle,draw=red,fill=red,scale=0.2] {};
\draw[->] (0.5, 1.4) -- (0.5,1.1)
node [right,midway] {$i$}
;
\node at (1.3,2) {$F$};
%%We draw the space E
\foreach \x in {1,2,...,60} {
\node at (1,1/\x) [circle,draw=blue,fill=blue,scale=0.1] {};
}
\foreach \x in {1,2,...,60} {
\draw (0,1/\x) -- (1,1/\x);
}
\draw (0,-1) -- (1,0);
\node at (1,0) (red point) [circle,draw=red,fill=red,scale=0.2] {};
\node at (1.3,0) {$E$};
%%The base space
\draw (0,-1.5) -- (1,-1.5);
\node at (1,-1.5) [circle,draw=red,fill=red,scale=0.2] {};
\node at (1.3,-1.5) {$B$};
%%arrows
\draw[->] (0.5, -1) -- (0.5,-1.3)
node [right,midway] {$p$}
;
%%left projection illustration
\draw (-0.5,1) -- (-0.5,-1);
\foreach \x in {1,2,...,60} {
\node at (-0.5,1/\x) [circle,draw=blue,fill=blue,scale=0.1] {};
}
\node at (-0.5,-1) [circle,draw=red,fill=red,scale=0.2] { };
\end{tikzpicture}